ARXPS-analysis of sputtered TiC, SiC and Ti0.5Si0.5C layers

Schier, V.; Michel, H.; Halbritter, J.

doi:10.1007/bf00321420

Cited by 84 publications

(46 citation statements)

References 13 publications

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“…The relatively sharp peaks of the TiC͑111͒, TiC͑200͒, Ti͑002͒, and TiC͑110͒ ͓denoted as ͑d͒ in Fig. In their angle resolved XPS study of sputtered TiC layers, Schier et al 28 reported about two titanium related peaks at 281.2 and 281.9 eV. The GIXRD results in Fig.…”

Section: Resultsmentioning

confidence: 88%

Enhancement of hemocompatibility on titanium implant with titanium-doped diamond-like carbon film evaluated by cellular reactions using bone marrow cell cultures in vitro

Feng¹,

Wang²,

Cheng³

et al. 2009

Journal of Vacuum Science &Amp; Technology B: Microelectronics and Nanometer Structures Processing, Measurement, and Phenomena

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The purpose of this study is to evaluate a new method to deposit a-C:H film with the biological acceptance of titanium as a protective coating material in biomedical applications. For this purpose, various amounts of titanium were incorporated into a-C:H films by a combined radio frequency and magnetron sputtering system. In order to realize the properties of a-C:H films with and without Ti, the specimens were evaluated by material analyses and cell culture. The Ti and TiC were embedded in and connected to an amorphous a-C:H matrix. The a-C:H∕Ti film has better capability of osteoblast differentiation than Ti and a-C:H, revealing that the biocompatibility of a-C:H containing Ti is obviously better than a-C:H. It is believed that the Ti plays an important role in enhancing the film’s adhesion and biocompatibility. Furthermore, it also revealed the issue of hemocompatibility and that blood/a-C:H∕Ti interactions as a function of surface roughness can affect the red blood cell (RBC) distributions in early tissue healing. The different surface roughness can result in various blood cell responses as investigated by RBC distribution and platelet aggregation.

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Section: Resultsmentioning

confidence: 88%

Enhancement of hemocompatibility on titanium implant with titanium-doped diamond-like carbon film evaluated by cellular reactions using bone marrow cell cultures in vitro

Feng¹,

Wang²,

Cheng³

et al. 2009

Journal of Vacuum Science &Amp; Technology B: Microelectronics and Nanometer Structures Processing, Measurement, and Phenomena

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“…Six different peaks can be discovered and attributed to the different compositions of Ti. [45][46][47][48] However, in the high resolution Ti 2p curve of the TF samples ( Fig. S2c in the ESI †), only two obvious peaks were found, and they correspond to TiO 2 2p 1/2 and TiO 2 2p 3/2 .…”

Section: Resultsmentioning

confidence: 99%

Truncated octahedral bipyramidal TiO₂/MXene Ti₃C₂ hybrids with enhanced photocatalytic H₂ production activity

et al. 2019

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“…Fits of the Ti 2p, C 1s, and Si 2p core‐level spectra were performed for a qualitative comparison of the samples. Binding energy ranges and boundary conditions for the fits were chosen according to the literature . Solid‐state magic angle spinning nuclear magnetic resonance (MAS NMR) spectra of 29 Si and 13 C were recorded at a spinning speed of 10 kHz on a Bruker Avance 400 MHz spectrometer featuring a 4 mm probe head and 4 mm ZrO 2 rotors.…”

Section: Methodsmentioning

confidence: 99%

An Activated TiC–SiC Composite for Natural Gas Upgrading via Catalytic Oxyhalogenation

et al. 2018

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Alkane oxyhalogenation has emerged as an attractive catalytic route for selective natural gas functionalization to important commodity chemicals, such as methyl halides or olefins. However, few systems have been shown to be active and selective in these reactions. Here, we identify a novel and highly efficient TiC–SiC composite for methane and ethane oxyhalogenation. Detailed characterization elucidates the kinetics and mechanism of the selective activation under reaction conditions to yield TiO2–TiC–SiC. This catalyst outperforms bulk TiO2, one of the best reported catalysts, reaching up to 85 % selectivity and up to 3 times higher titanium‐specific space‐time‐yield of methyl halides or ethylene. This is attributed to the fact that the active TiO2 phase generated in situ is embedded in the thermally conductive SiC matrix, facilitating heat dissipation thus improving selectivity control.

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ARXPS-analysis of sputtered TiC, SiC and Ti0.5Si0.5C layers

Cited by 84 publications

References 13 publications

Enhancement of hemocompatibility on titanium implant with titanium-doped diamond-like carbon film evaluated by cellular reactions using bone marrow cell cultures in vitro

Enhancement of hemocompatibility on titanium implant with titanium-doped diamond-like carbon film evaluated by cellular reactions using bone marrow cell cultures in vitro

Truncated octahedral bipyramidal TiO₂/MXene Ti₃C₂ hybrids with enhanced photocatalytic H₂ production activity

An Activated TiC–SiC Composite for Natural Gas Upgrading via Catalytic Oxyhalogenation

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ARXPS-analysis of sputtered TiC, SiC and Ti0.5Si0.5C layers

Cited by 84 publications

References 13 publications

Enhancement of hemocompatibility on titanium implant with titanium-doped diamond-like carbon film evaluated by cellular reactions using bone marrow cell cultures in vitro

Enhancement of hemocompatibility on titanium implant with titanium-doped diamond-like carbon film evaluated by cellular reactions using bone marrow cell cultures in vitro

Truncated octahedral bipyramidal TiO2/MXene Ti3C2 hybrids with enhanced photocatalytic H2 production activity

An Activated TiC–SiC Composite for Natural Gas Upgrading via Catalytic Oxyhalogenation

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Truncated octahedral bipyramidal TiO₂/MXene Ti₃C₂ hybrids with enhanced photocatalytic H₂ production activity