2022
DOI: 10.26434/chemrxiv-2022-bl6rx
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Aryl Dance Reaction of Arylheteroles

Abstract: We have discovered a 1,2-migration (aryl dance reaction) of the aryl group on heteroles. AlCl3 can efficiently convert C3-arylheteroles to C2-arylheteroles. Depending on the electron density of the substrate, conversion from C2- to C3-arylheteroles was also possible with catalytic Zn(OTf)2. A one-pot aryl dance/acylation or bromination, and arylation/aryl dance was also demonstrated.

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“…With an Altmetric score of 13, the preprint from Yamaguchi's team with the highest number of online mentions on the main "social networks" was posted on May 2022. [51] In slightly more than one month, the preprint has been mentioned on Twitter by 18 users located in Japan, Poland, United States of America, Vietnam and Germany. [52] In brief, with 24 preprints published in just three years, Yamaguchi's team likely preprints all its research output, fulfilling the principles and the objectives of open science.…”
Section: Other Teams In Other Countriesmentioning
confidence: 99%
“…With an Altmetric score of 13, the preprint from Yamaguchi's team with the highest number of online mentions on the main "social networks" was posted on May 2022. [51] In slightly more than one month, the preprint has been mentioned on Twitter by 18 users located in Japan, Poland, United States of America, Vietnam and Germany. [52] In brief, with 24 preprints published in just three years, Yamaguchi's team likely preprints all its research output, fulfilling the principles and the objectives of open science.…”
Section: Other Teams In Other Countriesmentioning
confidence: 99%