2009
DOI: 10.1039/b816113e
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Arylstibonic acids [H8(RSb)12O28]; precursors to organometallic isopolyoxostibonates [Na2H9(RSb)12O30]−, (R = aryl)

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Cited by 22 publications
(19 citation statements)
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“…Traumatic injury to the central nervous system (CNS) or neurodegenerative diseases can lead to extensive neuronal death and subsequent loss of function. 1,2 Cell transplantation therapies hold promise for regeneration and functional recovery; however, poor in vivo survival rates of traditionally transplanted cells which are injected in suspension limit the efficacy of such therapies. [3][4][5][6][7] This highlights the need for a strategy to improve the survival of transplanted neurons in vivo, which can be achieved via a neural tissue engineering approach of using a biomaterial scaffold as a transplantable cell support system.…”
Section: Introductionmentioning
confidence: 99%
“…Traumatic injury to the central nervous system (CNS) or neurodegenerative diseases can lead to extensive neuronal death and subsequent loss of function. 1,2 Cell transplantation therapies hold promise for regeneration and functional recovery; however, poor in vivo survival rates of traditionally transplanted cells which are injected in suspension limit the efficacy of such therapies. [3][4][5][6][7] This highlights the need for a strategy to improve the survival of transplanted neurons in vivo, which can be achieved via a neural tissue engineering approach of using a biomaterial scaffold as a transplantable cell support system.…”
Section: Introductionmentioning
confidence: 99%
“…Whereas the medium-sized cations Na + and K + template polyoxostibonates with a [(RSb) 12 O 30 ] core with one of the cations in a 10-coordinate site within the hexagonal antiprismatic channels, as previously reported, 1 …”
Section: ■ Conclusionmentioning
confidence: 70%
“…1,2 This structural arrangement is conserved for a variety of aryl R groups, crystallized with several different cations. 3 ESI-MS studies showed that the cluster units retained their integrity in MeCN solution.…”
Section: ■ Introductionmentioning
confidence: 99%
“…81 The structure of arylstibonic acids RSbO 3 H 2 (R = C 6 H 4 -4-Cl) has been probed by ESI-MS in MeCN. 82 The most significant peak in the mass spectrum corresponded to a species [H 7 (RSb) 12 O 28 ] -, related Sb 12 clusters were observed when different aryl groups were employed and the protons in this species were easily exchanged for sodium cations. In addition, an Sb 12 cluster was characterised by X-ray crystallography.…”
Section: Arsenic Antimony and Bismuthmentioning
confidence: 99%