2024
DOI: 10.1021/acs.chemrev.4c00296
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Aryne Chemistry: Generation Methods and Reactions Incorporating Multiple Arynes

Nayoung Kim,
Myungsoo Choi,
Sung-Eun Suh
et al.

Abstract: Arynes hold significance for the efficient fusion of (hetero) arenes with diverse substrates, advancing the construction of complex molecular frameworks. Employing multiple equivalents of arynes is particularly effective in the rapid formation of polycyclic cores found in optoelectronic materials and bioactive compounds. However, the inherent reactivity of arynes often leads to side reactions, yielding unanticipated products and underlining the importance of a detailed investigation into the use of multiple ar… Show more

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