2012
DOI: 10.1016/j.jpowsour.2012.06.068
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Ascorbic-acid-assisted recovery of cobalt and lithium from spent Li-ion batteries

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Cited by 422 publications
(224 citation statements)
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“…In the case of leaching with ascorbic acid (C 6 H 8 O 6 ), as displayed in Figure 6, previous research by Li et al [27] has shown that the LiCoO 2 within battery waste is dissolved by ascorbic acid and forms the soluble compound C 6 H 6 O 6 Li 2 . Concurrently, the cobalt is reduced from Co 3+ to the soluble Co 2+ species, C 6 H 6 O 6 Co, as the ascorbic acid is oxidized to dehydroascorbic acid (C 6 H 6 O 6 ) [28,29].…”
Section: Leaching In Sulfuric Acid With Different Reducing Agentsmentioning
confidence: 99%
“…In the case of leaching with ascorbic acid (C 6 H 8 O 6 ), as displayed in Figure 6, previous research by Li et al [27] has shown that the LiCoO 2 within battery waste is dissolved by ascorbic acid and forms the soluble compound C 6 H 6 O 6 Li 2 . Concurrently, the cobalt is reduced from Co 3+ to the soluble Co 2+ species, C 6 H 6 O 6 Co, as the ascorbic acid is oxidized to dehydroascorbic acid (C 6 H 6 O 6 ) [28,29].…”
Section: Leaching In Sulfuric Acid With Different Reducing Agentsmentioning
confidence: 99%
“…Compared with nickelecadmium (NieCd), nickelemetal hydride (NieMH), lead-acid, or other secondary batteries, LIBs have found wide application as electrochemical power sources in mobile communications and portable electronic devices due to their high power and energy density, long storage life, low self-discharge rate, high cell voltage, and wide operating temperature range [1]. As a consequence, the world's production of LIBs reached 2.05 billion in 2005 and 4.6 billion in 2010 [2].…”
Section: Introductionmentioning
confidence: 99%
“…[15] Of hydrometallurgical techniques for recovering metals, acid leaching is the most cost-effective, simple, and environmental friendly. Several studies have reported on the leaching of LiCoO 2 cathodic material from spent LIBs using inorganic acids, such as sulfuric (H 2 SO 4 ) [16e19], nitric (HNO 3 ) [21,22], and hydrochloric (HCl) [20] acids, and natural organic acids, such as citric (C 6 H 8 O 7 ) [23], DL-malic (C 4 H 5 O 6 ) [15],L-aspartic [12], ascorbic [1], and oxalic acids [5], as shown in Table 1. Table 1 summerized the leaching systems ever applied to recovery of lithium and cobalt from spent LIBs.…”
Section: Introductionmentioning
confidence: 99%
“…1,2 The annual global consumption of LIBs increased as high as 14.5% from 2006 to 2011, and the global consumption of LIBs reached 4.49 × 10 9 units in 2011. 3 Consequently, more consumption of LIBs implies more spent LIBs.…”
Section: ■ Introductionmentioning
confidence: 99%