Aspects of the Chemistry of the Cyclic Phosphonium Salt [Ph2PaP(Cl)N(SiMe3)C(tBu)=CbH(Pa–Cb)]Cl and the Related Diazadiphosphetidine [ClPaN(R)P(Cl)NbR(Pa–Nb)] [R = C(tBu)=C(H)SiMe3]

Hitchcock, Peter B.; Läppert, Michael F.; Layh, Marcus

doi:10.1002/(sici)1099-0682(199806)1998:6<751::aid-ejic751>3.0.co;2-5

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Cited by 10 publications

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Synthesis and Reactions of Mixed N,P Ligands

et al. 2005

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The gold complexes [RN=C(RЈ)CH(R)PPh 2 (AuCl)] (6a, RЈ = tBu; 6b, RЈ = Ad; R = SiMe 3 ) were synthesised from the ketimines RN=C(RЈ)CH(R)PPh 2 (2a, RЈ = tBu; 2b, RЈ = Ad; R = SiMe 3 ) and Me 2 SAuCl. The hydrolysis of the complexes to [H 2 NC(RЈ)=CHPPh 2 (AuCl)] (8a, RЈ = tBu; 8b, RЈ = Ad) in protic solvents was studied and the reaction intermediate [H(R) NC(tBu)=CHPPh 2 (AuCl)] (7a) was isolated. The ketimines were further reacted with PhPCl 2 to the cyclic phosphonium

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