2015
DOI: 10.1016/j.cemconres.2015.06.002
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ASR prevention — Effect of aluminum and lithium ions on the reaction products

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Cited by 63 publications
(21 citation statements)
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“…This mechanism was first suggested by Lawrence and Vivian (1961), who reported that the lithium silicates formed had low solubility producing a coating effectively protecting the reactive aggregates from further participation in ASR. This observation has been supported by many later studies (Kawamura and Fuwa, 2003;Mitchell et al, 2004;Feng et al, 2010;Leemann et al, 2014;Leemann et al, 2015;Kim and Olek, 2016;Guo et al, 2019). Leemann et al (2015) observed that the mitigating efficiency of LiNO 3 lessens with increasing the specific surface area of the reactive aggregates, due to the increased area to be covered by the lithium products.…”
Section: Formation Of a Physical Barriersupporting
confidence: 57%
“…This mechanism was first suggested by Lawrence and Vivian (1961), who reported that the lithium silicates formed had low solubility producing a coating effectively protecting the reactive aggregates from further participation in ASR. This observation has been supported by many later studies (Kawamura and Fuwa, 2003;Mitchell et al, 2004;Feng et al, 2010;Leemann et al, 2014;Leemann et al, 2015;Kim and Olek, 2016;Guo et al, 2019). Leemann et al (2015) observed that the mitigating efficiency of LiNO 3 lessens with increasing the specific surface area of the reactive aggregates, due to the increased area to be covered by the lithium products.…”
Section: Formation Of a Physical Barriersupporting
confidence: 57%
“…In one study, Al contained in SCM was reported to reduce SiO2 dissolution rate, while not inducing alterations in the morphology, structure, and composition of reaction products. [130] Nonetheless, the role of Al in the precipitation and thermodynamics of ASR gels has remained unclear. [131] Here, synthetic Al-containing ASR gels with compositions in the SiO2-Na2O-CaO-Al2O3-H2O (S-N-C-A-H) system, were also studied.…”
Section: Examining the Effect Of Aluminum On The Solubility Of Asr Gelmentioning
confidence: 99%
“…Besides excessive expansion, ASR reaction can result in cracking and microstructure degradation of cement composite, what was described among others in [28][29][30]. There are some methods preventing from ASR described in the literature that are based on applying appropriate additives, e.g., supplementary cementitious materials (SCM) like granulated blast furnace slag, fly ash, metakaolin [31], or metal ions [32]. Moreover, it is well known that microsilica is assumed as a very effective additive to mitigate ASR.…”
Section: Introductionmentioning
confidence: 99%