2023
DOI: 10.1002/ange.202301300
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Assembly of an A6L6 Anion Trigonal Antiprism and Binding of Glucopyranosides and Polyethylene Glycols (PEGs)

Abstract: Anion‐coordination‐driven assembly (ACDA) has proven to be a very effective strategy for the construction of polyhedral structures. Here we demonstrate that variation of the “angle” of the backbone of C3‐symmetric tris‐bis(urea) ligands, from triphenylamine to triphenylphosphine oxide, results in the change of the final construct from an A4L4 tetrahedron to a higher‐nuclearity, A6L6 trigonal antiprism (A=anion, herein PO43−; L=ligand). Most interestingly, this assembly features a huge hollow internal space tha… Show more

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