Assembly of MnIII ions into di-, tetra-, deca-nuclear coordination complexes, zero- to three-dimensional molecular frameworks: molecular spin flop to and short-range bulk magnetic spin flop ordering
Jayasree Kumar,
Ibtesham Tarannum,
Yan-Zhen Zheng
et al.
Abstract:Octahedral MnIII ions possess significant magnetic anisotropy due to second-order orbital contribution combined with Jahn-Teller distortion. This work reports the influence of O2N/O3N-donor ligands (H2L1, H2L2, H2L3, H3L4) towards the...
Three novel Mn(iii) vanhd complexes, namely [Mn(o-vanhd)(N3−)(H2O)]·CH3OH (1), [Mn(o-vanhd)(NCS−)(H2O)]·2CH3CN (2), and [Mn(o-vanhd)(H2O)]·ClO4·H2O (3), have been successfully synthesized using compartmental ligands paired with ancillary ligands.
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