2023
DOI: 10.1002/ange.202303037
|View full text |Cite
|
Sign up to set email alerts
|

Assembly of One to Four As4 Analogues, (Ge2As2)2− or (Ge3As)3−, in the Coordination Sphere of [PhM]+, [MesM]+, or M2+ (M=Zn, Cd, Hg)

Abstract: Pseudo‐tetrahedral units of p‐block atoms proved to be excellent building blocks for novel molecular architectures and for introducing new elemental combinations which are not otherwise accessible. In this work, we present a series of clusters obtained by reactions of binary Ge/As anions with [MPh2] (M=Zn, Cd, Hg; Ph=phenyl). The study is grounded on the fact that the binary reactant gained by extracting the solid ‘K2GeAs’ with ethane‐1,2‐diamine (en) co‐exists as (Ge2As2)2− and (Ge3As)3− in solution. This all… Show more

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

0
0
0

Publication Types

Select...

Relationship

0
0

Authors

Journals

citations
Cited by 0 publications
references
References 41 publications
0
0
0
Order By: Relevance

No citations

Set email alert for when this publication receives citations?