Assembly of Polynuclear<scp>Single‐molecule</scp>Magnets

Griffiths, Kieran; Блатов, В. А.; Kostakis, George E.

doi:10.1002/9783527809929.ch8

Cited by 2 publications

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References 109 publications

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“…In 2014, [176] R. Clérac et al reviewed recent results on 3d, 4 f, 5d-SMM focusing on the importance of the topological control of the metal ion building blocks to provide high-nuclearity molecules with controlled and enhanced magnetic properties. It was updated in 2018 [177] in a book chapter by G. E. Kostakis. It is interesting to note that, in 2015, [178] J. Tang et al illustrated the opposite strategy focusing on 4 f-SMM mainly obtained via serendipity approaches.…”

Section: Design Strategies and Approaches For High Performance 4 F-smmmentioning

confidence: 99%

Get under the Umbrella: A Comprehensive Gateway for Researchers on Lanthanide‐Based Single‐Molecule Magnets

Bernot

2023

Eur J Inorg Chem

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The number of scientific articles that need to be considered to cover a research topic is ever‐increasing and quite difficult for a newcomer to assimilate. This is particularly true in dynamic discipline like Molecular Magnetism. In order to help young researchers in this field, this article proposes a "review of reviews" also known as an "umbrella review" on lanthanide‐based single‐molecule magnets (4f‐SMM). As a preamble, various bibliographic search techniques and AI‐based tools for bibliographic search, indexing, and summarization are proposed and commented. Then, the main milestones in 4f‐SMM are identified. In the core of the paper, books, book articles, and reviews dealing with 4f‐SMM are contextualized and classified by subtopics. This article is therefore proposed as a gateway to the 4f‐SMM field.

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Section: Design Strategies and Approaches For High Performance 4 F-smmmentioning

confidence: 99%

Get under the Umbrella: A Comprehensive Gateway for Researchers on Lanthanide‐Based Single‐Molecule Magnets

Bernot

2023

Eur J Inorg Chem

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Multireversible Redox Processes in a Self‐Assembled Nickel Pentanuclear Bis(Triple‐stranded Helicate): Structural and Spectroscopic Characterizations in the Ni^II₅ and Ni^INi^II₄ Redox States

et al. 2021

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We previously reported the multireversible redox behavior of bis(triple‐helicate) pentanuclear complexes of the type [{M(μ‐bpp)3}2M(μ3‐X)]n+ (M=Mn, Fe with X=O and Co with X=OH) with rigid tetradentate binucleating 3,5‐bis(pyridine‐2‐yl)pyrazole (bpp−) ligand. In this article, we focus on the nickel derivative of this family, [{NiII(μ‐bpp)3}2NiII3(μ‐OH)]3+ (13+), which exhibits up to five reversible or quasi‐reversible one‐electron waves in CH3CN solution. The two one‐electron oxidized species as well as the one‐electron reduced species with respective compositions of 4NiII1NiIII (14+), 3NiII2NiIII (15+) and 1NiI4NiII (12+), were quantitatively generated by bulk electrolyses and spectroscopically characterized highlighting the high stability of this family of complexes in several redox states. In addition to the initial complex 13+, the mixed‐valence 12+ was also successfully characterized by single‐crystal X‐ray diffraction, allowing to locate the sites of successive reversible one‐electron events. 12+ is an unusual example of a multinuclear complex including the low‐valent Ni(I) state.

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Assembly of PolynuclearSingle‐moleculeMagnets

Cited by 2 publications

References 109 publications

Get under the Umbrella: A Comprehensive Gateway for Researchers on Lanthanide‐Based Single‐Molecule Magnets

Get under the Umbrella: A Comprehensive Gateway for Researchers on Lanthanide‐Based Single‐Molecule Magnets

Multireversible Redox Processes in a Self‐Assembled Nickel Pentanuclear Bis(Triple‐stranded Helicate): Structural and Spectroscopic Characterizations in the Ni^II₅ and Ni^INi^II₄ Redox States

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Assembly of PolynuclearSingle‐moleculeMagnets

Cited by 2 publications

References 109 publications

Get under the Umbrella: A Comprehensive Gateway for Researchers on Lanthanide‐Based Single‐Molecule Magnets

Get under the Umbrella: A Comprehensive Gateway for Researchers on Lanthanide‐Based Single‐Molecule Magnets

Multireversible Redox Processes in a Self‐Assembled Nickel Pentanuclear Bis(Triple‐stranded Helicate): Structural and Spectroscopic Characterizations in the NiII5 and NiINiII4 Redox States

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Multireversible Redox Processes in a Self‐Assembled Nickel Pentanuclear Bis(Triple‐stranded Helicate): Structural and Spectroscopic Characterizations in the Ni^II₅ and Ni^INi^II₄ Redox States