For current control in power conversion and motor drive systems, there exist three classic methods in the literature and they are the hysteresis current control (HCC), the sine pulse-width modulation (SPWM), and the space vector pulse width modulation (SVPWM). HCC is easy to implement, but has relatively large current harmonic distortion as the disadvantage. On the other hand, the SPWM and SVPWM use modulation technique, commonly together with at least one proportional-integral (PI) regulator to reduce load current ripples, and hence demanding more computation time. This paper aims to improve the performance of a recently proposed new current control method-the single-voltage-vector model predictive current control (SVV-MPCC), for synchronous reluctance motor (SynRMs) drives. To that end, a dual-voltage-vector model-free predictive current control (DVV-MFPCC) for SynRMs is proposed. Unlike the SVV-MPCC that applies only a single voltage vector per sampling period, the proposed DVV-MFPCC is capable of providing two successive segmentary current predictions in the next sampling period through all possible combinations from any two candidate switching states increasing the number of applicable switching modes from seven to nineteen and reducing the prediction error effectively. Moreover, the new control does not utilize any parameters of the SynRM nor its mathematical model. The performance is effectively enhanced compared to that of SVV-MPCC. The working principle of the DVV-MFPCC will be detailed in this paper. Finally, the SVV-MPCC, the single-voltage-vector model-free predictive current control (SVV-MFPCC), the dual-voltage-vector model predictive current control (DVV-MPCC), and the DVV-MFPCC are realized to control the stator currents of SynRM through a 32-bit microcontroller TMS320F28377S. Experimental results are provided to validate the new method and verify that the DVV-MFPCC performs better than do the SVV-MPCC, the SVV-MFPCC, and the DVV-MPCC.