A luminum alloys are preferred by the automotive industry due to their properties such as good castability, high strength and corrosion resistance [1]. These properties are mainly influenced by microstructure [2, 3]. Changes in microstructure can also affect porosity formation [4-7]. It is well known that the addition of Al-Ti-B master alloy into an Al-Si alloy will alter the microstructure from coarse α-Al to finer equiaxed dendritic morphology without changing the eutectic silicon morphology [8]. When it comes to the selection of master alloy, Al 3 Ti 3 B and Al 5 Ti 1 B grain refiners were compared in terms of effect on both microstructure and porosity formation [9]. It was concluded that Al 3 Ti 3 B grain refiner has a greater effect to prevent the porosity than Al 5 Ti 1 B grain refiner. As an alternative Al-Ti grain refiner of Al alloys, Al 3 B master alloy that contains no Ti was also studied. This master alloy contains B, AlB 2 and AlB 12 particles. AlB 12 can be unstable depending on the B content of the melt and reacts with Al to form AlB 2 which is a peritectic reaction [10, 11]. In casting applications, it has