A B S T R A C TMethane (CH4) is now considered a bridge fuel between present fossil (carbon) economy and desired renewables and this energy molecule is projected to play an important role in the global energy mix well beyond 2035. The atmospheric warming potential of CH4 is 28-36 times, when averaged over a 100-year period, that of carbon dioxide (CO2) and this necessitates a close scrutiny of global CH4 emissions inventory. As the second most abundant greenhouse gas (GHG), the annual global CH4 emissions were 645 million metric tons (MMT), accounting for 14.3% of the global anthropogenic GHG emissions. Of this, five key anthropogenic sources: agriculture, coal, landfills, oil and gas operations and wastewater together emitted 68% of all CH4 emissions. Landfills are ranked as the third highest anthropogenic CH4 emission source, behind agriculture and coal mines, and emissions from the waste sector are expected to reach almost 800 million metric tons CO2 equivalent (MMTCO2e) in 2015.The two largest economies spewed out 42% (14% (US) and 28% (China)) of the world's total greenhouse gas (GHG) emissions; these two countries are also the largest producers of municipal solid waste (MSW). The United States averages 250 MMT of MSW annually, of which about 63% enters landfills. In 2015, there were 2434 landfills in the United States and CH4 from these landfills accounted for 138 MMTCO2e released into the atmosphere and represents 17.7% of all US CH4 emissions. China had 580 landfills and treated 105 MMT of MSW in 2013. Methane produced from landfills contributes about 13% of total CH4 emissions in China. Almost 50% of landfills in China did not install efficient LFG collection and utilization systems to make them manageable so a great deal of CH4 and CO2 are emitted without intervention. Recent data show that globally, 45 billion cubic meters (bcm) of CH4 or 282 million barrels of oil equivalent (boe) was annually released from landfills into the atmosphere. Managing methane emission from landfills is a global challenge, though China lags behind in managed landfills that contribute to adverse health effects on the population. Moreover, the rich organic content of MSW in China indicates that CH4 emissions there may be underestimated. The China unmanaged landfill scenario is further duplicated in developing as well as in least-developed countries.This review starts with a dialog on CH4 emissions and climate change and the chemical changes the CH4 molecule undergoes in the atmosphere (Section 1). Section 2 deals with identification of global CH4 emissions from key sources, particularly anthropogenic, among those are agriculture, coal mines, landfills, oil and gas operations and wastewater. Although each of these sources is descriptive on their own, the focus of Section 3 is on landfills with particular emphasis on the United States and China, two largest producers of waste. The quantitative measurement of CH4 emissions is still uncertain so Section 4 is devoted to various CH4 estimation models, such as United States Environm...