“…All NMR experiments were carried out on an AMX-500 Bruker spectrometer using the same data acquisition and processing scheme (Redfield & Kuntz, 1975;Aue et al, 1976;Jeener et al, 1979;Kumar et al, 1980;Bax & Freeman, 1981;Braunsweiler & Ernst, 1983;Marion & Wuthrich, 1983;Shaka & Freeman, 1983;Bothner-By et al, 1984;Rance et al, 1984;Wider et al, 1984;Bax & Davis, 1985;Otting et al, 1986) previously used for the study of triple helices composed of (Gly-Pro-Hyp) n and of (Gly-Pro-Nleu) n sequences (Melacini et al, 1996a,b). For the hydrogen-exchange measurements, one-dimensional spectra were collected at 5°C over a period of 1 month.…”