Today, polyurethanes
are effectively not recycled and are made
principally from nonrenewable, fossil-fuel-derived resources. This
study provides the first high-resolution material flow analysis of
polyurethane flows through the U.S. economy, tracking back to fossil
fuels and covering polyurethane-relevant raw materials, trade, production,
manufacturing, uses, historical stocks, and waste management. According
to our analysis, in 2016, 2900 thousand tonnes (kt) of polyurethane
were produced in the United States and 920 kt were imported for consumption,
2000 kt entered the postconsumer waste streams, and 390 kt were recycled
and returned to the market in the form of carpet underlayment. The
domestic production of polyurethane consumed 1100 kt of crude oil
and 1100 kt of natural gas. With the developed polyurethane flow map,
we point out the limitation of the existing mechanical recycling methods
and identify that glycolysis, a chemical recycling method, can be
used to recycle the main components of postconsumer polyurethane waste.
We also explore how targeting biobased pathways could influence the
supply chain and downstream markets of polyurethane and reduce the
consumption of fossil fuels and the exposure to toxic precursors in
polyurethane production.