We describe measurements of the X-ray reflectance in the range 2 to 10 keV of samples representative of coated silicon wafers that are proposed for the fabrication of the XEUS (X-ray Evolving Universe Spectrometer) mission. We compare the reflectance of silicon samples coated with bare Pt, with that for samples with an additional 10nm thick carbon over-coating. We demonstrate a significant improvement in reflectance in the energy range ~1 to 4 keV, and at a grazing incidence angle of 10 mrad (0.57°). We consider the resulting effective area that could be attained with an optimized design of the XEUS telescope. Typically an improvement of 10 to 60 % in effective area, depending on photon energy, can be achieved using the carbon overcoat.