Chem. Commun.
 2024
DOI: 10.1039/d4cc02620a
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Asymmetric dearomatization of benzyl 1-naphthyl ethers via [1,3] O-to-C rearrangement

Hongkun Zeng,
Gang Wen,
Lili Lin
et al.

Abstract: An asymmetric dearomatization reaction of benzyl 1-naphthyl ethers accelerated by a chiral N,N′-dioxide/Co(ii) complex is disclosed. Experiment results indicated that the reaction proceeds via a tight ion-pair intermediate.

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