Org. Chem. Front.
 2024
DOI: 10.1039/d3qo01729j
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Asymmetric permanganate dihydroxylation of enoates: substrate scope, mechanistic insights and application in bicalutamide synthesis

Peilong Gu,
Shuangshuang Wang,
Xiangxiang Wen
et al.

Abstract: Chiral cinchoninium catalysed permanganate dihydroxylation of enoates with different substitution types, including challenging tetrasubstituted ones, provides good yields of chiral vicinal diols in up to 98% ee.

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