2021
DOI: 10.24820/ark.5550190.p011.446
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Asymmetric reactions involving isobenzopyrylium ion intermediates

Abstract: Isobenzopyrylium ions are highly reactive intermediates which have wide applications in synthetic chemistry. A range of catalytic reactions based on isobenzopyrylium, such as 1,2-nucleophilic addition, [4+2] and [3+2] cycloaddition provide a powerful protocol for constructing complex natural and unnatural products. Their asymmetric variations have been less explored, possibly owing to the lack of coordination sites within their planar structures. This mini-review summarizes the asymmetric transformations devel… Show more

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