Asymmetrical modification of Wells–Dawson POMs by Cu–phnz coordination polymers

Sha, Jingquan; Liang, Liye; Yang, Zhiwei; Wang, Cheng; Qu, Youle; Lv, Yuguang

doi:10.1016/j.inoche.2010.04.008

Inorganic Chemistry Communications

2010

DOI: 10.1016/j.inoche.2010.04.008

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Asymmetrical modification of Wells–Dawson POMs by Cu–phnz coordination polymers

Jingquan Sha

Liye Liang

Zhiwei Yang

et al.

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2013

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Polyoxometalate Insertion into Cu–pz Porous and Cu-bim Knighthead Coordination Polymers: [{Cu4(pz)5.5}{Cu2(2,2'-bim)3}0.5{P2W18O62}]·H2O

et al. 2013

Aust. J. Chem.

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The structure of crystallised {[Cu4(pz)5.5][Cu2(2,2′-bim)3]0.5[P2W18O62]}·H2O (1) (pz = pyrazine, bim = biimidazole) is reported. The crystal structure is characterised by cage-like pores [Cu8(pz)11]8+ of Cu ions linked through pz ligands. [P2W18O62]6– polyanions are capsulated into cage-like pores of [Cu8(pz)11]8+, forming ‘hamburger’-like units. Furthermore, the three-dimensional framework in 1 is achieved via copper-pyrazolate layers, binuclear copper-biimidazole subunits, and Dawson-type polyoxometalate clusters. The electrochemical properties of compound 1 were also studied in detail.

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Polyoxometalate Insertion into Cu–pz Porous and Cu-bim Knighthead Coordination Polymers: [{Cu4(pz)5.5}{Cu2(2,2'-bim)3}0.5{P2W18O62}]·H2O

et al. 2013

Aust. J. Chem.

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A new {P₂W₁₈} polyoxometalate cluster modified with copper complex based on pz, 2,2–bipy, and in situ amino acid

Zhou

et al. 2013

Journal of Coordination Chemistry

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Asymmetrical modification of Wells–Dawson POMs by Cu–phnz coordination polymers

Cited by 2 publications

References 30 publications

Polyoxometalate Insertion into Cu–pz Porous and Cu-bim Knighthead Coordination Polymers: [{Cu4(pz)5.5}{Cu2(2,2'-bim)3}0.5{P2W18O62}]·H2O

Polyoxometalate Insertion into Cu–pz Porous and Cu-bim Knighthead Coordination Polymers: [{Cu4(pz)5.5}{Cu2(2,2'-bim)3}0.5{P2W18O62}]·H2O

A new {P₂W₁₈} polyoxometalate cluster modified with copper complex based on pz, 2,2–bipy, and in situ amino acid

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Asymmetrical modification of Wells–Dawson POMs by Cu–phnz coordination polymers

Cited by 2 publications

References 30 publications

Polyoxometalate Insertion into Cu–pz Porous and Cu-bim Knighthead Coordination Polymers: [{Cu4(pz)5.5}{Cu2(2,2'-bim)3}0.5{P2W18O62}]·H2O

Polyoxometalate Insertion into Cu–pz Porous and Cu-bim Knighthead Coordination Polymers: [{Cu4(pz)5.5}{Cu2(2,2'-bim)3}0.5{P2W18O62}]·H2O

A new {P2W18} polyoxometalate cluster modified with copper complex based on pz, 2,2–bipy, and in situ amino acid

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A new {P₂W₁₈} polyoxometalate cluster modified with copper complex based on pz, 2,2–bipy, and in situ amino acid