Abstract-An empirical four-step mechanism has previously been proposed for describing ignition of heptane-air mixtures. This mechanism captures the l.,w-temperature and high-temperature ignition behavior as well as the intermediate-temperature behavior, between roughly 800 K and 1100 K, where a negative temperature dependence of the overall rate is observed. The present paper derives simplified overall rate formulas for ignition times from this four-step mechanism and uses those formulas to derive a temperatureexplicit model whose simplicity facilitates analysis of more complex ignition phenomena. Methods of activation-energy asymptotics are employed for the temperature-explicit model to investigate ignition in homogeneous, adiabatic systems, ignition by compressional heating in homogeneous systems, and structures and q uasisteady propagation velocities of cool flames in weakly strained mixing layers. I t is shown that, in the range of negative temperature dependence, there is a plateau in the ignition time when the criterion of thermal runaway is employed. Near this plateau region, cool flames with three-zone structures can propagate at velocities that increase with increasing initial temperature. Besides providing qualitative descriptions of ignition processes for hydrocarbon-air mixtures, the results lead to quantitative predictions that can be compared with experiment.