2020
DOI: 10.5194/acp-2019-867
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Atmospheric fate of two relevant unsaturated ketoethers: kinetics, products and mechanisms for the reaction of hydroxyl radicals with (<i>E</i>)-4-methoxy-3-buten-2-one and 1-(<i>E</i>)-1-methoxy-2-methyl-1-penten-3-one

Abstract: <p><strong>Abstract.</strong> The kinetics of the gas-phase reactions of hydroxyl radicals with two unsaturated methoxy-ketones at (298 ± 3) K and 1 atm of synthetic air have been studied for the first time using the relative rate technique in an environmental reaction chamber by in situ FTIR spectrometry. The rate coefficients obtained using propene and isobutene as reference compounds were (in units… Show more

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