This paper presents the results of measurements of the surface ozone (O 3 ), oxides of nitrogen (NO x ), methane (CH 4 ) and total non-methane hydrocarbons (TNMHCs) in a rural coastal location at Kannur (11.9°N, 75.4°E, 5 m asl), India from November 2009 to December 2011. The diurnal cycle for surface O 3 had a peak in the afternoon and declined during nighttime. The maximum and minimum mixing ratio of surface O 3 was observed in winter and monsoon seasons respectively. NO x concentration was high during mid-night to early morning and low during noontime. The diurnal variations of mixing ratios for NO x and O 3 were anti-correlated. Monthly average maximum (2.26 ± 0.44 ppmv) and minimum (0.43 ± 0.19 ppmv) CH 4 concentrations were observed in December and August respectively. The diurnal variations of CH 4 were similar to that of NO x . A CH 4 buildup was observed during early morning hours throughout the observational period. On an annual basis, the maximum, minimum and average total NMHCs were (25.45 ± 6.58 ppbv), (13.84 ± 4.31 ppbv), and (19.23 ± 5.56 ppbv) respectively at the observational site. Analysis of O 3 , NO, NO 2 , CH 4 and NMHC have been carried out and the correlation between O 3 and its precursors is discussed detailed. Further, the diurnal variation of O 3 over a free tropospheric region at Ooty, a hill station lying in the Western Ghats region of south India on clear sky days in February 2011 is also reported for a comparison.