Atom and step economical synthesis of acyclic quaternary centers <i>via</i> iridium-catalyzed hydroarylative cross-coupling of 1,1-disubstituted alkenes

Cooper, Phillippa; Dalling, Andrew G.; Farrar, Elliot H. E.; Aldhous, Timothy P.; Grélaud, Simon; Lester, Eleanor; Feron, Lyman; Kemmitt, Paul D.; Grayson, Matthew N.; Bower, John F.

doi:10.1039/d2sc02790a

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Atom and step economical synthesis of acyclic quaternary centers via iridium-catalyzed hydroarylative cross-coupling of 1,1-disubstituted alkenes

Abstract: Quaternary benzylic centers are accessed with high atom and step economy by intermolecular Ir-catalyzed hydroarylation of non-polarized 1,1-disubstituted alkenes.

Cited by 2 publications

References 42 publications

Catalytic Addition of C–H Bonds Across C–C π-Bonds

Catalytic Addition of C–H Bonds Across C–C π-Bonds

A theoretical study of the mechanisms, regio- and enantioselectivities associated with rhodium-catalyzed allylic alkylation reactions using hard benzylzinc nucleophiles

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