“…Recently, indirect atomic absorption methods were employed for the determination of aliphatic secondary amines, aldehydes, and thiols (8)(9)(10). In each of these indirect atomic absorption spectrophotometry (IAAS) methods, a metallic precipitate formed with the analyte or with the product was incorporated in the final procedure before filtration and finally digested for analysis.…”
“…Recently, indirect atomic absorption methods were employed for the determination of aliphatic secondary amines, aldehydes, and thiols (8)(9)(10). In each of these indirect atomic absorption spectrophotometry (IAAS) methods, a metallic precipitate formed with the analyte or with the product was incorporated in the final procedure before filtration and finally digested for analysis.…”
“…Another separation method involves the precipitation of the thiol as the silver salt with alcoholic silver nitrate. After isolation of the precipitate, it is converted to silver ion and analyzed by atomic absorption spectroscopy (54).…”
The surface-enhanced Raman scattering of benzenethiol was investigated in a silver sol. It was found that benzenethiol was chemisorbed dissociatively on the silver surface by rupture of its S-H bond and the benzenethiolate formed on adsorption was bound to silver via its sulphur atom. Using the electromagnetic surface selection rule, the orientation of the benzene ring with respect to the surface plane could not be determined conclusively. However, it seemed likely that benzenethiol was adsorbed face-on to the silver surface.
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