Atomic Layer Deposition of Cu Electrocatalysts on Gas Diffusion Electrodes for CO<sub>2</sub> Reduction

Lenef, Julia D.; Lee, Si Young; Fuelling, Kalyn M.; Rivera Cruz, Kevin E.; Prajapati, Aditya; Delgado Cornejo, Daniel O.; Cho, Tae H.; Sun, Kai; Alvarado, Eugenio; Arthur, Timothy S.; Roberts, Charles A.; Hahn, Christopher; McCrory, Charles C. L.; Dasgupta, Neil P.

doi:10.1021/acs.nanolett.3c02917

Cited by 5 publications

(1 citation statement)

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“…To achieve the formation and selectivity of C 2+ products with longer electroreduction times, Lenef and co-workers, for the first time, demonstrated the use of ALD Cu as the sole active catalyst, which was fabricated using plasma-enhanced ALD (PEALD) and deposited on 3D porous carbon GDE. 330 This approach allows for the fabrication of tunable catalyst size and loading, ensuring a conformal coating deep into the 3D electrode surface without clogging the surface pores. The electrochemical CO 2 reduction revealed the PEALD Cu catalyst deposited with 510 cycles produced a remarkable total FE of 75.2% for C 2+ products including FE of 42.2% for C 2 H 4 at −0.94 V vs. RHE (Fig.…”

Section: Ald-designed Catalysts For Co2 Valorizationmentioning

confidence: 99%

Atomic/molecular layer deposition strategies for enhanced CO₂ capture, utilisation and storage materials

Olowoyo,

Gharahshiran,

Zeng

et al. 2024

Chem. Soc. Rev.

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Section: Ald-designed Catalysts For Co2 Valorizationmentioning

confidence: 99%

Atomic/molecular layer deposition strategies for enhanced CO₂ capture, utilisation and storage materials

Olowoyo,

Gharahshiran,

Zeng

et al. 2024

Chem. Soc. Rev.

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Atomically Dispersed Metal Catalysts for the Conversion of CO₂ into High‐Value C₂₊ Chemicals

Yang,

Liu,

Lin

et al. 2024

Advanced Materials

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The conversion of carbon dioxide (CO2) into value‐added chemicals with two or more carbons (C2+) is a promising strategy that can not only mitigate the anthropogenic CO2 emissions but also reduce the excessive dependence on fossil feedstocks. In recent years, atomically dispersed metal catalysts (ADCs), including single‐atom catalysts (SACs), dual‐atom catalysts (DACs) and single‐cluster catalysts (SCCs), emerged as the attractive candidates for CO2 fixation reactions due to their unique properties, such as the maximum utilization of active sites, tunable electronic structure, and the efficient elucidation of catalytic mechanism, etc. In this review, we provide an overview of significant progress in the synthesis and characterization of ADCs utilized in photocatalytic, electrocatalytic and thermocatalytic conversion of CO2 towards high‐value C2+ compounds. To provide insights for designing efficient ADCs towards the C2+ chemical synthesis originating from CO2, the key factors that influence the catalytic activity and selectivity are highlighted. Finally, the relevant challenges and opportunities are discussed to inspire new ideas for the generation of CO2‐based C2+ products over ADCs.This article is protected by copyright. All rights reserved

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Transition metal (Fe, Co, Ni)-doped cuprous oxide nanowire arrays as self-supporting catalysts for electrocatalytic CO2 reduction reaction to ethylene

Min,

Wang,

et al. 2024

Applied Surface Science

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Atomic Layer Deposition of Cu Electrocatalysts on Gas Diffusion Electrodes for CO₂ Reduction

Cited by 5 publications

References 61 publications

Atomic/molecular layer deposition strategies for enhanced CO₂ capture, utilisation and storage materials

Atomic/molecular layer deposition strategies for enhanced CO₂ capture, utilisation and storage materials

Atomically Dispersed Metal Catalysts for the Conversion of CO₂ into High‐Value C₂₊ Chemicals

Transition metal (Fe, Co, Ni)-doped cuprous oxide nanowire arrays as self-supporting catalysts for electrocatalytic CO2 reduction reaction to ethylene

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Atomic Layer Deposition of Cu Electrocatalysts on Gas Diffusion Electrodes for CO2 Reduction

Cited by 5 publications

References 61 publications

Atomic/molecular layer deposition strategies for enhanced CO2 capture, utilisation and storage materials

Atomic/molecular layer deposition strategies for enhanced CO2 capture, utilisation and storage materials

Atomically Dispersed Metal Catalysts for the Conversion of CO2 into High‐Value C2+ Chemicals

Transition metal (Fe, Co, Ni)-doped cuprous oxide nanowire arrays as self-supporting catalysts for electrocatalytic CO2 reduction reaction to ethylene

Contact Info

Product

Resources

About

Atomic Layer Deposition of Cu Electrocatalysts on Gas Diffusion Electrodes for CO₂ Reduction

Atomic/molecular layer deposition strategies for enhanced CO₂ capture, utilisation and storage materials

Atomic/molecular layer deposition strategies for enhanced CO₂ capture, utilisation and storage materials

Atomically Dispersed Metal Catalysts for the Conversion of CO₂ into High‐Value C₂₊ Chemicals