2024
DOI: 10.1038/s41467-024-51000-w
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Atomic-precision control of plasmon-induced single-molecule switching in a metal–semiconductor nanojunction

Youngwook Park,
Ikutaro Hamada,
Adnan Hammud
et al.

Abstract: Atomic-scale control of photochemistry facilitates extreme miniaturisation of optoelectronic devices. Localised surface plasmons, which provide strong confinement and enhancement of electromagnetic fields at the nanoscale, secure a route to achieve sub-nanoscale reaction control. Such local plasmon-induced photochemistry has been realised only in metallic structures so far. Here we demonstrate controlled plasmon-induced single-molecule switching of peryleneanhydride on a silicon surface. Using a plasmon-resona… Show more

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