The Coulomb-capture ratios of muons in the metallic solid solutions Au-Ag, Te-Se, Cd-Mg, Nb-V, and Cu-Ni have been measured via the muonic Lyman series intensities. In the case of Nb-V, targets of three stoichiometric ratios were investigated. The results do not agree with the per-atom ratios A(Z/Z') assumed to be equal to Z/Z' ("FermiTeller law") or (Z/Z') 7/6. They are better, but also not in general well, reproduced bydeviations occuring in cases of different metallic radii.