Emerging evidence highlights the role of social comparison in competition and cooperation, yet the dynamics among competitiveness, cooperativeness, and social comparison orientation (SCO) remain underexplored. In the present study, we sought to unravel these complex interplays employing graphical Gaussian models (GGMs) and characterize the network structures utilizing cross‐sectional data derived from 1073 Chinese participants. A pre‐registered independent sample (n = 1348) served to examine the replicability and robustness of our initial findings. Moreover, we explored the Bayesian networks (i.e., directed acyclic graphs) to delve into their probabilistic directed dependencies. Our analysis identified an interpersonal co‐opetition network where SCO bridges competitiveness and cooperativeness, emphasizing the key influence of the desire to surpass others. We also found a significant gender effect on the levels of these orientations but not on the network patterns. Additionally, the replication sample offered validation for the resultant network structure and its key nodes. In sum, these findings provide a new insight into the symbiotic relationship between competitiveness and cooperativeness within the framework of social comparison, offering significant theoretical and practical implications.