Aurora borealis: Stochastic cellular automata simulations of the excited‐state dynamics of oxygen atoms

Abstract

Emissions from the 1S and 1D excited states of atomic oxygen play a prominent role in creating the dramatic light displays (aurora borealis) seen in the skies over polar regions of the Northern Hemisphere. A probabilistic asynchronous cellular automaton model described previously [Seybold, Kier, and Cheng, J Phys Chem 1998, 102, 886–891] has been applied to the excited‐state dynamics of atomic oxygen. The model simulates the time‐dependent variations in ground (3P) and excited‐state populations that occur under user‐defined probabilistic transition rules for both pulse and steady‐state conditions. Although each trial simulation is itself an independent “experiment,” deterministic values for the excited‐state emission lifetimes and quantum yields emerge as limiting cases for large numbers of cells or large numbers of trials. Stochastic variations in the lifetimes and emission yields can be estimated from repeated trials. ©1999 John Wiley & Sons, Inc. Int J Quant Chem 75: 751–756, 1999

Cellular automata models of kinetically and thermodynamically controlled reactions

“…Applications of the first-order model to atomic and molecular excited-state phenomena have also been presented [21,22]. In this report we examine the application of the first-order model to the phenomena of kinetic and thermodynamic reaction control in order to demonstrate the capabilities of this approach for kinetic problems.…”