We offer a theoretical and experimental study of the single-photon photoionization of Ne III. The high photon flux and the high-resolution capabilities of the Advanced Light Source at the LBNL were employed to measure absolute photoionization cross sections. The resulting spectrum has been benchmarked against high accuracy relativistic Breit-Pauli R-matrix calculations. A large close-coupling wave function expansion which comprises up to 58 fine-structure levels of the residual ion Ne IV of configurations 2s 2 2p 3 , 2s2p 4 , 2p 5 , 2s 2 2p 2 3s, 2s 2 2p 2 3p and 2s 2 2p 2 3d was included. A complete identification of the measured features was achieved by considering seven low-lying levels of Ne III. We found that the photoionization cross-section (σ P I ) exhibits the presence of prominent resonances in the low-energy region near the ionization thresholds that correspond to low-lying levels. These include high-peak narrow resonances with almost zero background introduced by relativistic effects. However, there does not exist a significant contribution to σ P I from relativistic effects at the high-energy interval of the present study.