Prolonged computer-related work can be linked to musculoskeletal disorders (MSD) in the upper limbs and improper posture. In this regard, we report on developing resources supporting improper posture studies based on motion capture sensors. These resources were used to create a baseline detector for the automated detection of improper sitting postures, which was next used to evaluate the applicability of Hjorth’s parameters—Activity, Mobility and Complexity—on the specific classification task. Specifically, based on accelerometer data, we computed Hjorth’s time-domain parameters, which we stacked as feature vectors and fed to a binary classifier (kNN, decision tree, linear SVM and Gaussian SVM). The experimental evaluation in a setup involving two different keyboard types (standard and ergonomic) validated the practical worth of the proposed sitting posture detection method, and we reported an average classification accuracy of up to 98.4%. We deem that this research contributes toward creating an automated system for improper posture monitoring for people working on a computer for prolonged periods.