This research develops and validates new decomposition models for hourly direct Normal Irradiance (DNI) estimations for Southern African data. Localised models were developed using data collected from the Southern African Universities Radiometric Network (SAURAN). Clustered areas within Southern Africa were identified, and the developed cluster decomposition models highlighted the potential advantages of grouping data based on shared geographical and climatic attributes. This clustering approach could enhance decomposition model performance, particularly when local data are limited or when data are available from multiple nearby stations. Further, a regional Southern African decomposition model, which encompasses a wide spectrum of climatic regions and geographic locations, exhibited notable improvements over the baseline models despite occasional overestimation or underestimation. The results demonstrated improved DNI estimation accuracy compared to the baseline models across all testing and validation datasets. These outcomes suggest that utilising a localised model can significantly enhance DNI estimations for Southern Africa and potentially for developing similar models in diverse geographic regions worldwide. The overall metrics affirm the substantial advancement achieved with the regional model as an accurate decomposition model representing Southern Africa. Two stations were used as a validation study, as an application example where no localised model was available, and the cluster and regional models both outperformed the comparative decomposition models. This study focused on validating the model for hourly DNI in Southern Africa within a range of Kt-intervals from 0.175 to 0.875, and the range could be expanded and validated for future studies. Implementing accurate decomposition models in developing countries can accelerate the adoption of renewable energy sources, diminishing reliance on coal and fossil fuels.