Mobile station (MS) localization in a cellular network is appealing to both industrial community and academia, due to the wide applications of location-based services. The main challenge is the unknown one-bound (OB) and multiple-bound (MB) scattering environment in dense multipath environment. Moreover, multiple base stations (BSs) are required to be involved in the localization process, and the precise time synchronization between MS and BSs is assumed. In order to address these problems, hybrid time of arrival (TOA), angle of departure (AOD), and angle of arrival (AOA) measurement model from the serving BS with the synchronization error is investigated in this paper. In OB scattering environment, four linear least square (LLS), one quadratic programming and data fusion-based localization algorithms are proposed to eliminate the effect of the synchronization error. In addition, the Cramer-Rao lower bound (CRLB) of our localization model on the root mean-square error (RMSE) is derived. In hybrid OB and MB scattering environment, a novel double identification algorithm (DIA) is proposed to identify the MB path. Simulation results demonstrate that the proposed algorithms are capable to deal with the synchronization error, and LLS-based localization algorithms show better localization accuracy. Furthermore, the DIA can correctly identify the MB path, and the RMSE comparison of different algorithms further prove the effectiveness of the DIA.