2024
DOI: 10.1002/ange.202409332
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Axial Ligand Enables Synthesis of Allenylsilane through Dirhodium(II) Catalysis

Wendeng Li,
Rui Wu,
Hao Ruan
et al.

Abstract: Described herein is a dirhodium(II)‐catalyzed silylation of propargyl esters with hydrosilanes, using tertiary amines as axial ligands. By adopting this strategy, a range of versatile and useful allenylsilanes can be achieved with good yields. This reaction not only represents a SN2'‐type silylation of the propargyl derivatives bearing a terminal alkyne moiety to synthesize allenylsilanes from simple hydrosilanes, but also represents a new application of dirhodium(II) complexes in catalytic transformation of c… Show more

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