2023
DOI: 10.1039/d2me00274d
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Aza-bicyclooctadiene/tetracyclooctane couples as promising photoswitches for molecular solar thermal energy storage applications

Abstract: The scrutiny of molecular photoswitches has received utmost attention owing to their plethora of promising applications. Bicyclooctadiene/Tetracyclooctane (BOD/TCO) couple is recently recognized as a suitable photoswitching system for molecular solar...

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Cited by 6 publications
(10 citation statements)
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“…This infers that the effect on Δ G str is only marginal if the bridgehead and closest unsaturated C of bicyclodiene are replaced by N. The observed trend of variation in storage energy with position of N in bicyclodiene-based photoswitches with different bridge lengths resembles that of the NBD/QC system and the recently reported BOD/TCO system. 59 This indicates that the position of N is crucial for modulating the storage energy in bicyclodiene-based photoswitches with different bridge lengths. Notably, the presence of N in the unsaturated position improves the storage energy, whereas replacing the bridgehead C with N may degrade the energy storage properties in the studied bicyclodiene based photoswitches.…”
Section: Resultsmentioning
confidence: 99%
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“…This infers that the effect on Δ G str is only marginal if the bridgehead and closest unsaturated C of bicyclodiene are replaced by N. The observed trend of variation in storage energy with position of N in bicyclodiene-based photoswitches with different bridge lengths resembles that of the NBD/QC system and the recently reported BOD/TCO system. 59 This indicates that the position of N is crucial for modulating the storage energy in bicyclodiene-based photoswitches with different bridge lengths. Notably, the presence of N in the unsaturated position improves the storage energy, whereas replacing the bridgehead C with N may degrade the energy storage properties in the studied bicyclodiene based photoswitches.…”
Section: Resultsmentioning
confidence: 99%
“…58 In aza-bicyclodiene switches, N may internally involve a push–pull mechanism and the properties can be tuned without reducing the energy storage density due to the mass of N, and thus is advantageous over bulky group substituents. 59…”
Section: Resultsmentioning
confidence: 99%
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“…1,[5][6][7] Hitherto, a variety of switching couples, like diazobenzene and NBD-QC, have been extensively investigated for applications in photopharmocology, vision restoration, molecular solar thermal energy storage (MOST), and so forth. 6,[8][9][10][11][12] Indeed, the exploration of other molecular switching couples to derive exceptional properties and myriad applications still persists.…”
Section: Introductionmentioning
confidence: 99%