Aza‐Cope Rearrangement—Mannich Cyclizations for the Formation of Complex Tricyclic Amines: Stereocontrolled Total Synthesis of (.+‐.)‐Gelsemine.

Abstract

Alkaloids U 0600Aza-Cope Rearrangement-Mannich Cyclizations for the Formation of Complex Tricyclic Amines: Stereocontrolled Total Synthesis of (±)-Gelsemine. -(EARLEY, W. G.; JACOBSEN, J. E.; MADIN, A.; MEIER, G. P.; O'DONNELL, C.; OH, T.; OLD, D. W.; OVERMAN*, L. E.; SHARP, M. J.; J.