Aza-substitution, benzo-annulation effects and catalytic activity of β-octaphenyl-substituted tetrapyrrolic macroheterocyclic cobalt complexes. I. heterogeneous catalysis

Вашурин, А. С.; Майзлиш, В. Е.; Kuzmin, Ilya; Петров, О. А.; Razumov, Mikhail; Pukhovskaya, S. G.; Голубчиков, О. А.; Койфман, О. И.

doi:10.1007/s10847-016-0674-4

Cited by 5 publications

(2 citation statements)

References 37 publications

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“…We previously found the macrocycle's structure and its coordination ability to play the key role for catalytic process. [56][57][58] DTC oxidation takes place in kinetic region upon constant oxygen and catalyst concentration as well as solution's pH. We approved earlier non-catalytic oxidation of DTC to be almost non-existent (k obs = 1.7•10 -5 s -1 ).…”

Section: Cobalt Complexes With Water-soluble Phthalocyaninesmentioning

confidence: 60%

Catalytically Active Systems of Cobalt Complexes with Wa-ter-Soluble Phthalocyanines

Вашурин¹,

Kuzmin²,

Razumov³

et al. 2018

MHC

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The work reports catalytic properties of series of cobalt phthalocyanines peripherally substituted with consistently changing sulfonated fragments. Data on heterogenization of cobalt phthalocyaninates onto organic and inorganic polymers are provided. Comparing catalytic activity of the macrocycles in dependence on structure and peripheral substituent as well as polymer carrier's type is given. Application of cobalt phthalocyanine's sulfonic acids for fine synthesis of thiuram E upon both homogeneous and heterogeneous catalysis is shown to be prospective.

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Section: Cobalt Complexes With Water-soluble Phthalocyaninesmentioning

confidence: 60%

Catalytically Active Systems of Cobalt Complexes with Wa-ter-Soluble Phthalocyanines

Вашурин¹,

Kuzmin²,

Razumov³

et al. 2018

MHC

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“…Процесс электроосаждения в целом не зависит от природы заместителя во фталоцианиновом макрокольце: окислительно-восстановительные процессы, происходящие на периферии макроцикла фталоцианина, не участвуют (или участвуют слабо) в электрохимических процессах. Это согласуется с механизмами каталитического действия металлофталоцианинов как в гомогенном, так и гетерогенном процессе сочетания тиолов в дисульфиды [89,[92][93][94].…”

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Chemistry of Liquid Systems and Functional Materials Based on Coordination Compounds of Linear and Cyclic Polypyrroles

2023

Izv. Vyssh. Uchebn. Zaved. Khim. Khim. Tekhnol.

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The review presents a generalization of research on the chemistry of solutions and materials based on linear and cyclic polypyrrole compounds carried out at the Department of Inorganic Chemistry of the Ivanovo State University of Chemistry and Technology. The review focuses on key areas related to synthetic approaches to the preparation of boron complexes with pyrrole derivatives, as well as complexes of a wide range of metals of the periodic system with substituted derivatives of the phthalocyanine ligand. Spectroscopic, luminescent, acid-base properties of synthesized compounds and their practical application in sensor systems are considered separately. In addition, the possibilities of obtaining hybrid and functional materials, including derivatives of borondipyrrins and tetrapyrrole macroheterocyclic compounds, which have increased catalytic and biological activity in liquid-phase processes are shown. For citation: Vashurin A.S., Bobrov A.V., Botnar A.A., Bychkova A.N., Gornukhina O.V., Grechin O.V., Erzunov D.A., Kovanova M.A., Ksenofontova K.V., Kuznetsov V.V., Lefedova O.V., Latypova A.R., Litova N.A., Marfin Yu.S., Pukhovskaya S.G., Tarasyuk I.A., Tikhomirova T.V., Rumyantsev E.V., Usoltsev S.D., Filippov D.V. Chemistry of liquid systems and functional materials based on coordination compounds of linear and cyclic polypyrroles. ChemChemTech [Izv. Vyssh. Uchebn. Zaved. Khim. Khim. Tekhnol.]. 2023. V. 66. N 7. P. 76-97. DOI: 10.6060/ivkkt.20236607. 6840j.

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Novel Co(II) phthalocyanines of extended periphery and their water-soluble derivatives. Synthesis, spectral properties and catalytic activity

Filippova

Вашурин

Znoyko

et al. 2017

Journal of Molecular Structure

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Aza-substitution, benzo-annulation effects and catalytic activity of β-octaphenyl-substituted tetrapyrrolic macroheterocyclic cobalt complexes. I. heterogeneous catalysis

Cited by 5 publications

References 37 publications

Catalytically Active Systems of Cobalt Complexes with Wa-ter-Soluble Phthalocyanines

Catalytically Active Systems of Cobalt Complexes with Wa-ter-Soluble Phthalocyanines

Chemistry of Liquid Systems and Functional Materials Based on Coordination Compounds of Linear and Cyclic Polypyrroles

Novel Co(II) phthalocyanines of extended periphery and their water-soluble derivatives. Synthesis, spectral properties and catalytic activity

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