Azamacrocyclic-based metal organic frameworks: Design strategies and applications

Stackhouse, Chavis A.; Ma, Shengqian

doi:10.1016/j.poly.2018.01.036

Cited by 46 publications

(27 citation statements)

References 101 publications

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“…However, no attempt has been made thus far to combine this linker with macrocyclic complexes, which provide pre-formed SBUs of another type (two vacant trans axial positions in the coordination sphere of the metal ion) with an additional benefit of extremely high thermodynamic stability and kinetic inertness (Melson, 1979;Yatsimirskii & Lampeka, 1985). At the same time, such SBUs have been used successfully for the assembly of a number of coordination polymers (Lampeka & Tsymbal, 2004;Suh & Moon, 2007;Suh et al, 2012;Stackhouse & Ma, 2018), including those with some other Si-containing carboxylates (Gavrish et al, 2020a;Gavrish et al, 2020b).…”

Section: Chemical Contextmentioning

confidence: 99%

Crystal structure of the one-dimensional coordination polymer formed by the macrocyclic [Ni(cyclam)]²⁺cation and the dianion of diphenylsilanediylbis(4-benzoic acid)

Gavrish¹,

Shova²,

Cazacu³

et al. 2020

Acta Cryst E

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The asymmetric unit of the title compound, catena-poly[[[(1,4,8,11-tetraazacyclotetradecane-κ4 N 1,N 4,N 8,N 11)nickel(II)]-μ-4,4′-(diphenylsilanediyl)dibenzoato-κ2 O:O′] sesquihydrate], {[Ni(C26H18O4Si)(C10H24N4)]·1.5H2O} n , consists of the halves of the centrosymmetric macrocyclic cation and the C 2-symmetric dicarboxylate dianion and of the water molecule of crystallization. The Ni2+ ion is coordinated by the four secondary N atoms of the macrocyclic ligand characterized by the most energetically favourable trans-III conformation and two mutually trans O atoms of the carboxylate, forming a slightly tetragonally elongated trans-N4O2 octahedron. The crystals are composed of parallel polymeric chains of the macrocyclic cations linked by the anions of the acid running along the [101] direction. Each polymeric chain is bonded to four neighbouring ones via water molecules providing O—H...O hydrogen bonds to the non-coordinated carboxyl O atoms to form a three-dimensional supramolecular network.

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Section: Chemical Contextmentioning

confidence: 99%

Crystal structure of the one-dimensional coordination polymer formed by the macrocyclic [Ni(cyclam)]²⁺cation and the dianion of diphenylsilanediylbis(4-benzoic acid)

Gavrish¹,

Shova²,

Cazacu³

et al. 2020

Acta Cryst E

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“…Coordination compounds of cyclam-like tetradentate azamacrocyclic ligands (cyclam = 1,4,8,11-tetraazacyclotetradecane) have attracted considerable attention because of their high thermodynamic stability, kinetic inertness, unusual redox properties and spectroscopic features (Melson, 1979;Yatsimirskii & Lampeka, 1985). Transition-metal complexes of this type of equatorial ligand possess two trans vacant sites in the axial positions and are suitable building blocks for the construction of metal-organic frameworks (MOFs) with potential applications in many areas including sorption, separation, gas storage, heterogeneous catalysis etc (Lampeka & Tsymbal, 2004;Suh & Moon, 2007;Suh et al, 2012;Stackhouse & Ma, 2018;Lee & Moon, 2018). The Cu II complexes of N 3 ,N 10 -dialkyl-substituted diazacyclam (diazacyclam = 1,3,5,8,10,12-hexaazacyclotetradecane), readily obtainable via template-directed Mannich condensation of bis(ethylenediamine) complexes with formaldehyde and primary amines (Costisor & Linert, 2000), represent widespread systems in this kind of investigation.…”

Section: Chemical Contextmentioning

confidence: 99%

Crystal structure oftrans-diaqua(3,10-dimethyl-1,3,5,8,10,12-hexaazacyclotetradecane)copper(II) pamoate

et al. 2019

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The asymmetric unit of the title compound, trans-diaqua(3,10-dimethyl-1,3,5,8,10,12-hexaazacyclotetradecane-κ4 N 1,N 5,N 8,N 12)copper(II) 4,4′-methylenebis(3-hydroxynaphthalene-2-carboxylate), [Cu(C10H26N6)(H2O)2](C23H14O6) {[Cu(L)(H2O)2](pam), where L = 3,10-dimethyl-1,3,5,8,10,12-hexaazacyclotetradecane and pam = dianion of pamoic acid} consists of two independent halves of the [Cu(L)(H2O)2]2+ cation and one dicarboxylate anion. The CuII atoms, lying on inversion centres, are coordinated by the four secondary N atoms of the macrocyclic ligands and the mutually trans O atoms of the water molecules in a tetragonally elongated octahedral geometry. The average equatorial Cu—N bond length is significantly shorter than the average axial Cu—O bond length [2.007 (10) and 2.486 (18) Å, respectively]. The macrocyclic ligand in the complex cations adopts the most energetically stable trans-III conformation. The complex cations and anions are connected via hydrogen-bonding interactions between the N—H groups of the macrocycles and the O—H groups of coordinated water molecules as the proton donors and the O atoms of the carboxylate as the proton acceptors into layers lying parallel to the (1\overline{1}1) plane.

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“…An alternative is the use of preformed SBUs with fixed vacant sites in the coordination spheres of the metal ions, for example, metal complexes of tetraazamacrocyclic ligands. In addition to the presence of two trans-axial positions, such SBUs are characterized by high thermodynamic stability and kinetic inertness (Melson, 1979;ISSN 2053ISSN -2296 # 2020 International Union of Crystallography Yatsimirskii & Lampeka, 1985), implying preservation of their structural features during the formation of MOFs (Lampeka & Tsymbal, 2004;Suh & Moon, 2007;Suh et al, 2012;Lee & Moon, 2018;Stackhouse & Ma, 2018).…”

Section: Introductionmentioning

confidence: 99%

A 2D coordination polymer assembled from a nickel(II) tetraazamacrocyclic cation and 4,4′-(dimethylsilanediyl)diphthalate(3–) linker

Gavrish

Shova²,

Cazacu³

et al. 2020

Acta Crystallogr C

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The preformed nickel(II) complex of the 14-membered macrocyclic ligand 1,4,8,11-tetraazacyclotetradecane (cyclam, L), when treated with 4,4 0 -(dimethylsilanediyl)diphthalic acid (H 4 A) in a DMF/H 2 O mixture (4:1 v/v) under heating, leads to [Ni(L)] 3 (HA) 2 Á3DMF (IÁDMF). Redissolution of this compound in a DMF/H 2 O/MeOH mixture (4:1:30 v/v/v) with mild acidification under gentle heating results in the formation of a similar compound but containing water and methanol molecules of crystallization, [Ni(L)] 3 (HA) 2 Á5H 2 OÁ2MeOH (IIÁH 2 O). At lower temperature and concentration of reactants and longer reaction time, single crystals of composition {[{Ni(L)} 3 (HA) 2 ]Á4CH 3 OH} n (IIÁMeOH) were isolated. Single-crystal X-ray diffraction analysis of this compound, which, according to PXRD is isostructural with (1,4,8,11-tetraazacyclotetradecane-4 N)trinickel(II)] methanol tetrasolvate], {[Ni 3 (C 18 H 13 O 8 Si) 2 (C 10 H 24 N 4 ) 3 ]Á4CH 3 OH} n . It is built up of the monoprotonated tricarboxylate HA 3À ligand coordinated in a monodentate manner in the axial positions of two crystallographically independent Ni II cations, one of which is located on a crystallographic inversion centre. Both metal ions adopt a slightly tetragonally elongated trans-N 4 O 2 octahedral geometry. The compound has a lamellar structure with polymeric layers oriented parallel to the (102) plane, which are in turn linked via hydrogen bonds involving protonated carboxylic acid groups of the ligand. Bulk compounds IÁDMF and IIÁH 2 O were characterized by FT-IR and diffuse reflectance spectroscopy and thermogravimetry, which provide evidence of their structural differences. research papers Acta Cryst. (2020). C76, 419-426 Gavrish et al. A 2D nickel(II) polymer 423 Figure 3(a) The crystal structure of IIÁMeOH, viewed down the [201] direction, and (b) a view of the layer parallel to the (102) plane. Methyl groups on the Si atom, H atoms on the C atoms of the macrocycle and the carboxylate groups, the minor-disorder component of the cyclam ligand and methanol molecules of crystallization have been omitted. Hydrogen bonds are shown as dashed lines. research papers Acta Cryst. (2020). C76, 419-426 Gavrish et al. A 2D nickel(II) polymer 425

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Azamacrocyclic-based metal organic frameworks: Design strategies and applications

Cited by 46 publications

References 101 publications

Crystal structure of the one-dimensional coordination polymer formed by the macrocyclic [Ni(cyclam)]²⁺cation and the dianion of diphenylsilanediylbis(4-benzoic acid)

Crystal structure of the one-dimensional coordination polymer formed by the macrocyclic [Ni(cyclam)]²⁺cation and the dianion of diphenylsilanediylbis(4-benzoic acid)

Crystal structure oftrans-diaqua(3,10-dimethyl-1,3,5,8,10,12-hexaazacyclotetradecane)copper(II) pamoate

A 2D coordination polymer assembled from a nickel(II) tetraazamacrocyclic cation and 4,4′-(dimethylsilanediyl)diphthalate(3–) linker

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Azamacrocyclic-based metal organic frameworks: Design strategies and applications

Cited by 46 publications

References 101 publications

Crystal structure of the one-dimensional coordination polymer formed by the macrocyclic [Ni(cyclam)]2+cation and the dianion of diphenylsilanediylbis(4-benzoic acid)

Crystal structure of the one-dimensional coordination polymer formed by the macrocyclic [Ni(cyclam)]2+cation and the dianion of diphenylsilanediylbis(4-benzoic acid)

Crystal structure oftrans-diaqua(3,10-dimethyl-1,3,5,8,10,12-hexaazacyclotetradecane)copper(II) pamoate

A 2D coordination polymer assembled from a nickel(II) tetraazamacrocyclic cation and 4,4′-(dimethylsilanediyl)diphthalate(3–) linker

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Crystal structure of the one-dimensional coordination polymer formed by the macrocyclic [Ni(cyclam)]²⁺cation and the dianion of diphenylsilanediylbis(4-benzoic acid)

Crystal structure of the one-dimensional coordination polymer formed by the macrocyclic [Ni(cyclam)]²⁺cation and the dianion of diphenylsilanediylbis(4-benzoic acid)