Three chiral manganese(III) Schiff-base complexes [Mn(R,R-Salcy)(CH3OH)(N3)], [Mn(S,S-Salcy)(DMF)(N3)] (both monomers by X-structure determination) and the trinuclear complex (X-ray structure) {[Mn(R,R-Salcy)(H2O)]2[μ-Ni(CN)4]}·3CH3OH·H2O [Salcy = N,N′-(1,2-cyclohexanediylethylene)bis(salicylideneiminato)dianion)] have been synthesised. The trimeric complex shows weak antiferromagnetic interactions between the adjacent Mn(III) ions.