Azo Compounds

Sandler, Stanley R.

doi:10.1016/b978-0-08-092557-8.50018-5

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“…Diazenes have been studied since the end of the 19th century . They are often highly colored being intense orange, yellow, red, blue, or green depending on their molecular structure and have been used in the dying, printing, and textile industries.…”

Section: Introductionmentioning

confidence: 99%

Synthesis of Bisbicyclo[1.1.1]pentyldiazene. The Smallest Bridgehead Diazene

Hossain

Timberlake

2001

J. Org. Chem.

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Bisbicyclo[1.1.1]pentyldiazene, the smallest bicyclic azo compound, has been synthesized from the precursor [1.1.1]propellane via synthesis of N,N'-bis(bicyclo[1.1.1]pentyl)sulfamide and azoxybicyclo[1.1.1]pentane. The UV absorption of this diazene at 382 nm indicates that the compound is the trans isomer. Conversion to the cis isomer by irradiation was not possible because of attainment of a photostationary state. However, on the basis of the photochemical studies, the absorption of the cis-[1.1.1] isomer is estimated to be 384 nm.

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Section: Introductionmentioning

confidence: 99%