B(C6F5)3-catalyzed hydrogermylation of enones: a facile route to germacycles

Xiong, Jiangkun; Yan, Maying; Jin, Lvnan; Song, Weihong; Xiao, Lei; Xu, Dong; Zhai, Chunyang; Stephan, Douglas W.; Guo, Jing

doi:10.1039/d3ob01402a

Org. Biomol. Chem.

2023

DOI: 10.1039/d3ob01402a

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B(C₆F₅)₃-catalyzed hydrogermylation of enones: a facile route to germacycles

Jiangkun Xiong,

Maying Yan,

Lvnan Jin

et al.

Abstract: Organogermacycles are prepared in good to excellent yields by B(C6F5)3 mediated domino hydrogermylation reaction of enones with dihydrogermanes.

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2024

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Visible‐Light‐Driven Germyl Radical Generation via EDA‐Catalyzed ET–HAT Process

Yoshizawa,

Li,

Matsuyama

et al. 2024

Chemistry A European J

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We have established a facile and efficient protocol for the generation of germyl radicals by employing photo‐excited electron transfer (ET) in an electron donor‐acceptor (EDA) complex to drive hydrogen‐atom transfer (HAT) from germyl hydride (R3GeH). Using a catalytic amount of EDA complex of commercially available thiol and benzophenone derivatives, the ET‐HAT cycle smoothly proceeds simply upon blue‐light irradiation without any transition metal or photocatalyst. This protocol also affords silyl radical from silyl hydride.

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Visible‐Light‐Driven Germyl Radical Generation via EDA‐Catalyzed ET–HAT Process

Yoshizawa,

Li,

Matsuyama

et al. 2024

Chemistry A European J

View full text Add to dashboard Cite

show abstract

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B(C₆F₅)₃-catalyzed hydrogermylation of enones: a facile route to germacycles

Abstract: Organogermacycles are prepared in good to excellent yields by B(C6F5)3 mediated domino hydrogermylation reaction of enones with dihydrogermanes.

Cited by 1 publication

References 49 publications

Visible‐Light‐Driven Germyl Radical Generation via EDA‐Catalyzed ET–HAT Process

Visible‐Light‐Driven Germyl Radical Generation via EDA‐Catalyzed ET–HAT Process

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