B(C6F5)3‐Catalyzed N‐Allylation of Hydrazines with Allylic Alcohols
Boxia Xu,
Ji Yang,
Zhen Yao
et al.
Abstract:A N‐allylation of monosubstituted acyl hydrazines with allylic alcohols has been developed by using B(C6F5)3 catalysis. This protocol allows for convenient access to various synthetically useful N‐allylated hydrazine products in 48‐96% yields with broad substrate scope and wide functional group compatibility. The operationally simple reaction proceeds without calling for stringent removal of air and moisture, and can be readily scaled up to gram scale. Preliminary mechanistic studies support that the generatio… Show more
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