We report the most general expression for the chiral charges of a Z gauge boson coming from an E 6 unification model, as a function of the electroweak parameters and the charges of the U (1) factors in the chain of subgroups. These charges are valid for an arbitrary Higgs sector and only depend on the branching rules of the E 6 fundamental representation and the corresponding rules for the fermionic representations of their subgroups. By assuming E 6 unification, the renormalization group equations (RGE) allow us to calculate the electroweak parameters at low energies for most of the chains of subgroups in E 6 . From RGE and unitary conditions, we show that at low energies there must be a mixing between the gauge boson of the standard model hypercharge and the Z . From this, it is possible to delimit the preferred region in the parameter space for a breaking pattern in E 6 . In general, without unification, it is not viable to determine this region; however, for some models and under certain assumptions, it is possible to limit the corresponding parameter space. By using the most recent upper limits on the cross-section of extra gauge vector bosons Z decaying into dileptons from the ATLAS data at 13 TeV with accumulated luminosities of 36.1 fb −1 and 13.3 fb −1 , we report the 95% C.L. lower limits on the Z mass for the typical E 6 benchmark models. We also show the contours in the 95% C.L. of the Z mass bounds for the entire parameter space of E 6 .