In order to elucidate
the origin of coalbed methane (CBM) in the
Jiergalangtu block of Erlian Basin, Inner Mongolia of China, gas components,
stable isotope tests of 22 gas samples, radioisotope dating measurements,
and water quality analysis of 15 coproduced water samples were evaluated.
On account of the geochemical data and genetic indicators, including
C1/C1–n
, C1/(C2 + C3), and CO2/(CO2 + CH4) (CDMI) values, δ13C(CO2), Δδ13C(CO2–CH4
), δ15N, and 3He/4He combined with vitrinite reflectance (Ro) (0.29–0.48%, avg.
0.35%) of Saihantala formation, the results indicate that methane
in the Jiergalangtu block is mostly dominated by primary and secondary
biological gas, 40.91% of the gas samples are secondary biogas and
primary biogas accounts for 59.19%. Among them, methyl-type fermentation
accounts for 31.82%, and carbon dioxide (CO2) reduction
makes up 68.18%. CO2 reduction generally occurs region-wide
but is mainly associated with the central part of the block, where
CO2 depletion and 13C enrichment take place
correspondingly. Methane and CO2 δ13C
almost tend to isotopically light along the margin of the block, indicating
that gas generation is significantly affected by the methyl-type fermentation
pathway. Meanwhile, the genesis analysis of other gas components in
CBM is also investigated, CO2 is mainly the associated
product of microbial methanogenesis, and nitrogen (N2)
is primarily from the atmosphere with a little amount from the earth’s
crust. Furthermore, the formation time of coalbed water has been dissected
based on the hydrogeochemical properties of the coproduced water samples.
The coalbed water exhibit a Na–HCO3 and Na–HCO3–Cl type and have a total dissolved solid (TDS) value
ranging from 2458.58 to 5579.1 mg/L, with an average of 3440.55 mg/L.
Moreover, comprehensive analysis of δD(H2O), δ18O(H2O), δ13CDIC, and
the radioisotope dating index [3H, 14C(Fm) and 14C(BP)] indicates that the coalbed water was formed in the
Quaternary Pleistocene and rarely replenished by the present surface
water. The mechanism of CBM accumulation is basically sorted out by
synthesizing the history of burial, heat, and hydrocarbon generation.
The CBM formation can be divided into four stages. That is, microbial
gas production approximately began at the beginning of the Early Cretaceous
and reached the peak of thermogenic gas production in the middle and
late Early Cretaceous. At the end of the Early Cretaceous, strata
possibly began to uplift, and denudation led to gas escape. From Neogene
to Pleistocene, glacial meltwater tended to penetrate into coalbed
on a large scale, and N2 and CO2 also entered
the coal seams, stimulating abundant secondary biological gas generation.
Since Holocene, geological conditions including temperature and TDS
have become hostile to biogas generation, and biogas generation tends
to stop. Therefore, the Jiergalangtu block mainly represents sealed
primary biological gas and secondary biological gas in CBM reservoirs.