2023
DOI: 10.1021/acs.inorgchem.3c01700
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BaMo3O10 Polymorphs with Tunable Symmetries and Properties

Abstract: Polymorphism is a well-known but important phenomenon in the field of solid-state chemistry. Crystalline materials can form various polymorphs and present drastically varied physical and chemical properties. Herein, systematic exploration of the BaO-MoO 3 binary system leads to the discovery of a new barium molybdate, α-BaMo 3 O 10 . The temperature-dependent phase transition from α-BaMo 3 O 10 to β-BaMo 3 O 10 is confirmed. The tunable linear and nonlinear optical properties induced by the phase transition ar… Show more

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