The aim of this work is to study the entanglement harvesting between two graphene layers inside a planar microcavity. Applying time-dependent perturbation theory it is shown that nonclassical correlations between electrons in different layers are obtained through the exchange of virtual photons. Considering different initial states of the electrons and the vacuum state of the electromagnetic field, the negativity measure that quantifies the entanglement, is computed through the photon propagator, for time scales smaller than the light-crossing time of the double layer. The results are compared with those obtained for hydrogenic probes and pointlike Unruh-deWitt detectors, showing that for different initial states, entangled X states and more general entangled reduced matrices are obtained, which enlarge the classification of bipartite quantum states. * email: jsardenghi@gmail.com, fax number: +54-291-4595142 1 In turn, a time-window function is included in the interaction to allows the interaction to occur in a finite time.