Base-catalyzed oxygenation of 2,6-di-t-butylanilines

Regioselective formation of peroxyquinolatocobalt(III) complexes in the oxygenation of 2,6-di-t-butylphenols with cobalt(II) Schiff-base complexes

“…of (2) (Table 1) contrary to the case of (3) whose t-butyl groups are magnetically equivalent. The non-equivalency 123.9 ( 20) 106.5…”

Professor Tetsuo Nozoe and My Tropylium Ion Chemistry

“…In a similar fashion, the salts of radical cations of various polycyclic aromatic hydrocarbons, such as naphthalene, [37] biphenylene, [37b] anthracene, [37b,38] and fluorene, [39] were isolated as single crystals, and their X-ray structures determined. [37b] These studies were further extended to investigate the cationic systems of various sulfur-containing compounds such as thiophene, [40] 1,2- [41] and 1,4-dithiin, [42] and oligothiophenes [43] from the dimer to the octamer, all fully or partially annelated by BCO units. As expected, all of these compounds gave stable radical cations and dications.…”

Studies of Synthetic Macrocyclic Complexes of Co (II) and Mn( II) in the Catalytic Oxidation of Hydroquinones

“…Methyl substituted Me 6 dibenzo [1, 4,8,11] tetraazacyclotetradecaene-N 4 complexes of Co(II) and Mn(II) respectively were prepared by template method. All the reactants were of AR grade purchased from TCI, India.…”

“…[3][4][5][6] The catalytic oxidation of methyl hydroquinone by tetramethyl tetraaza cobalt macrocyclic complexes has also been reported. [7][8][9][10][11][12] We carried out the autooxidation of methoxy and some other hydroquinones in presence of Co(II) and Mn(II) complexes of hexamethyl tetraaza macrocyclic ligands A and B. …”