Based on atom transfer radical polymerization method preparation of fluoropolymer superhydrophobic films

Wei, Zefei; Liu, W.L.; Xiao, Chaohu; Tian, Dong; Fan, Zhenzhong; Sun, Xin; Wang, Xinqiang

doi:10.1016/j.tsf.2010.07.052

Cited by 17 publications

(12 citation statements)

References 20 publications

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“…15 Poly(dimethylsiloxane) and uoropolymers are advantageous for generating superhydrophobic surfaces alone or in combination with other polymers as well as inorganic nanoparticles. [16][17][18] For example, superhydrophobic surfaces can be fabricated by casting a micelle solution of polystyrene-bpoly(hexauorobutyl-methacrylate) in 1,1,2-trichlorotriuoroethane onto a glass substrate. 16 However, most of the methods for preparation of superhydrophobic surfaces cannot be easily scaled up because of the very strict preparation conditions, complicated preparation processes, time consuming nature and high cost.…”

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confidence: 99%

“…[16][17][18] For example, superhydrophobic surfaces can be fabricated by casting a micelle solution of polystyrene-bpoly(hexauorobutyl-methacrylate) in 1,1,2-trichlorotriuoroethane onto a glass substrate. 16 However, most of the methods for preparation of superhydrophobic surfaces cannot be easily scaled up because of the very strict preparation conditions, complicated preparation processes, time consuming nature and high cost. As a result, applications of such superhydrophobic surfaces have been limited in practice.…”

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confidence: 99%

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Facile preparation of superhydrophobic coating by spraying a fluorinated acrylic random copolymer micelle solution

Li¹,

Zhao²,

Yuan³

2013

Soft Matter

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A superhydrophobic polymer coating is prepared by spraying a fluorinated acrylic random copolymer micelle solution. The surface morphology of the coating can be controlled by the solvent, and the possible formation mechanism of the superhydrophobic coating is proposed. The coating displays anti-icing properties and resistance to low temperature.Scheme 1 Polymerization of fluorinated acrylic copolymer (FAC).

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confidence: 99%

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confidence: 99%

Facile preparation of superhydrophobic coating by spraying a fluorinated acrylic random copolymer micelle solution

Li¹,

Zhao²,

Yuan³

2013

Soft Matter

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“…However, it is an active metal that does not resist corrosion enough, especially in the presence of chloride anions [ 110 ]. Therefore, several of the solutions were tested to protect copper and its alloys from corrosion [ 10 , 111 , 112 ]. In this regard, triazole derivatives such as benzotriazole (BTA) are the first 1 H -1,2,3-triazole compounds investigated as corrosion inhibitors for copper and its alloys and so they are classified as effective corrosion inhibitors for copper surfaces [ 113 , 114 , 115 , 116 ].…”

Section: 123-triazoles As Corrosion Inhibitorsmentioning

confidence: 99%

An Overview on the Performance of 1,2,3-Triazole Derivatives as Corrosion Inhibitors for Metal Surfaces

Hrimla

Bahsis

Laamari

et al. 2021

IJMS

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This review accounts for the most recent and significant research results from the literature on the design and synthesis of 1,2,3-triazole compounds and their usefulness as molecular well-defined corrosion inhibitors for steels, copper, iron, aluminum, and their alloys in several aggressive media. Of particular interest are the 1,4-disubstituted 1,2,3-triazole derivatives prepared in a regioselective manner under copper-catalyzed azide-alkyne cycloaddition (CuAAC) click reactions. They are easily and straightforwardly prepared compounds, non-toxic, environmentally friendly, and stable products to the hydrolysis under acidic conditions. Moreover, they have shown a good efficiency as corrosion inhibitors for metals and their alloys in different acidic media. The inhibition efficiencies (IEs) are evaluated from electrochemical impedance spectroscopy (EIS) parameters with different concentrations and environmental conditions. Mechanistic aspects of the 1,2,3-triazoles mediated corrosion inhibition in metals and metal alloy materials are also overviewed.

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“…Such materials are of interest because of their use in creating antibiotic resistance materials, their non-linear optical properties, and use as rheological modifiers by patterning surfaces on the nanometre scale. Wei et al 10 also synthesized a polystyrene-blockpoly(2,2,3,4,4,4-hexafluorobutyl-methacrylate) (St-b-HFMA) diblock copolymer by ATRP. This material was then dissolved in the solvent 1,1,2-trichlorotrifluoroethane (Freon 113) forming a micellar solution.…”

Section: Introductionmentioning

confidence: 99%

Synthesis and dissipative particle dynamics simulation of cross-linkable fluorinated diblock copolymers: self-assembly aggregation behavior in different solvents

Lin

Wen

Cai

et al. 2011

Phys. Chem. Chem. Phys.

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Developing microstructures, such as low molecular aggregates, spherical micelles and multi-compartment micelles, is an expanding area of research in Materials Science. By applying an atom transfer radical polymerization (ATRP) process to cross-linkable fluorinated diblock copolymers and analyzing the data we are able to demonstrate the potential for developing films with different micro-structures for additional biological research. Applying the Dissipative Particle Dynamic (DPD) Method, Transmission Electron Microscopy (TEM) and Scanning Electron Microscopy (SEM) techniques to cross-linkable fluorinated diblock copolymers of (methyl methacrylate-co-hydroxyethyl methacrylate-co-butyl methacrylate)-b-2-(perfluoroalkyl)ethyl methacrylate (MMA-co-HEMA-co-BMA-b-FMA) we were able to analyze the structures and their relationships to the aggregation of various microstructure formations through the use of various solvents in the process. For the self-assembly of the cross-linkable diblock copolymer in solutions, the DPD simulation results are only in qualitative agreement with experimental data of aggregate morphologies and sizes. This suggests an improved approach to creating materials and methods necessary for studying microstructures in films used in other research areas. Our work examines whether using selective solvents can be easily extended to prepare aggregates with different morphologies, which is an effective shortcut to obtain films with different microstructures. DPD simulation can be considered as an adjunct to experiments and provides other valuable information for the experiment.

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Based on atom transfer radical polymerization method preparation of fluoropolymer superhydrophobic films

Cited by 17 publications

References 20 publications

Facile preparation of superhydrophobic coating by spraying a fluorinated acrylic random copolymer micelle solution

Facile preparation of superhydrophobic coating by spraying a fluorinated acrylic random copolymer micelle solution

An Overview on the Performance of 1,2,3-Triazole Derivatives as Corrosion Inhibitors for Metal Surfaces

Synthesis and dissipative particle dynamics simulation of cross-linkable fluorinated diblock copolymers: self-assembly aggregation behavior in different solvents

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